London Dispersion: London dispersion forces result from instantaneous nonpermanent dipoles created by random electron motion. London dispersion forces
are present in all molecules and are directly proportional to molecular size.
- are very weak forces of attraction between molecules resulting from:
- momentary dipoles occurring due to uneven electron distributions in neighbouring molecules as they approach one another
- the weak residual attraction of the nuclei in one molecule for the electrons in a neighbouring molecule.The more electrons that are present in the molecule, the stronger the dispersion forces will be.
- Dispersion forces are the only type of intermolecular force operating between non-polar molecules, for example, dispersion forces operate between hydrogen (H2) molecules, chlorine (Cl2) molecules, carbon dioxide (CO2) molecules, dinitrogen tetroxide (N2O4) molecules and methane (CH4) molecules.